Deepdeep Because they do.
First off, OLED is the superior display tech, to clear that away. Infinite contrast ratios and very fast response times are the biggest benefits of OLED vs LCD
PWM (Pulse Width Modulation, or specifically, multi strobe PWM, the one that most have an issue with here from what I gather) is a technology used to dim the screen by flashes in appropriate duty cycles.
By design, at 100% brightness (duty cycle), PWM should never be a thing. There are LCD's which suffer from this too, it's not OLED specific. It's a panel specific thing.
From what I gather, low PWM frequency (different from refresh rate/vertical frequency of a display) is mostly used as a way to cut corners in a device by using a cheaper controller for adjusting the backlight of the panel, thus resulting in the low refresh rate flicker we have on modern OLED smartphones and older LCD displays.
Ever since VESA made the Freesync certification (monitors) a standard, most of the low end backlight contollers have been cleared (or use a very high pwm dimming frequency, imperceptible to humans)
Perhaps if some governing body like VESA jumps in the same way for phones might yield to much better OLED's for people suffering from PWM dimming related eyestrain
However, Freesync cert is still not a viable way to 100% be sure the display is without flicker across it's entire brightness range too! As I've mentioned, it's still panel specific
Yes, desktop OLED's/newer modern LCD's are able to dim themselves without PWM flicker across most of it's brightness range (with slight/unnoticable flicker on lower ranges for OLEDs, LCD's mostly have none), for example:
Aorus 48" OLED (CTRL+F for "PWM" and you'll see the graph)
LG CX TV
LG C2 TV
Alienware AW3423DW
Razer Blade
Other Razer Blade
Asus Zenbook Flip 14"
Asus Zenbook 14x
So, what's stopping phone manifacturers to pick up? I don't really know, I wish we'd get a proper reason other than the usual "OLED's cannot be PWM dimmed due to issues in form of black crush, color banding etc. on DC dimmed panels"
I pressume this is an issue if someone wants single digit nits of brightness on a OLED, surely not an issue if aiming for 20-60nits. But, modern phones don't seem to care about the lower end of the brightness spectrum, it's all about the upper range (how high it can go!!!)
The Lumia 650, Wiko WIM and S20 FE 5G (DC dimmed till 30%, so ~150nits I assume, which can be a obnoxious brightness setting at night, but only this particular model as the 4G one doesn't seem to incorporate the same panel)
The former two are irrelevant as they're way too old to be useful in any way possible.
So, to answer the question of your topic, yes, they do and almost all modern OLED smartphones (apart from the S20 FE 5G from my knowledge) have PWM dimming at 100% brightness.
It shouldn't be there at 100% brightness, but it sadly is due to (my theory) manifacturers cutting corners in display panel backlight controllers.
I wouldn't rely on those "DC Dimming / Anti-Flicker" modes most manifacturers provide, as it is a hardware issue not a software one (I've yet to read some proper explanation as to what each manifacturer does to "achieve DC dimming" with their software solutions)
So, keep an eye out for notebookcheck reviews for PWM dimming frequency measurements for smartphones, they seem to be the only reliable ones on the current market (RTings does desktop panels only)